actually both (c) and (d) are correct.
d is called the contrapostive.
as for the third option
now let's say that the third option is incorrect then we can have (p -> r) false even when the left hand side is true.
but p -> r false means p = True and R = False. Now for the left hand side to be true Q has to be false and true at the same time. Since (p -> q) demands q to be false whereas (q -> r) demands q to be true. which is never possible hence that is also a tutology.