Identification of whether DCFL or CFL?
The very basic thing to look out first, is whether you can generate that language using a PDA or not ? Relate it with stack and just by using push and pop can you generate it ? If so, its a CFL. Now if the PDA that you are using, is deterministic at each step, that is you are clear about the next move every single time, then it's a DCFL, otherwise if there is any non determinism involved, that is there are some steps where more than one move is possible, and you are not certain about the action, then its CFL. While remembering the fact that DCFL is a proper subset of CFL.
Ex: let L= {a^{n}b^{n}}, it is CFL because, with the help of PDA (push down automata), we can recognize it. We have n a's followed by n b's. we can push all a and corresponding to each b, we can pop a. if they are equal stack will be empty. if a are more, stack will have a. if stack becomes empty before finishing string, it means we have more b. It is DCFL as well because, we know we have to push a and pop for b, the action is deterministic.
On the other hand, {ww^{R, }where w is a string of a and b} is non deteministic CFL because till half of the length, we have to push and then we have to pop. but we dont know length. So at each step, we will push the next symbol and pop the previous one to see which one works. so it is non deteminsitic. So a CFL will be either deterministic or non deterministic.