$R$ $=$ $\left \{ \left ( x,y \right )| x\equiv 7-y \right \}$
condition is $x + y =7$
Relation will contain;
$$\left \{ ,\left ( 6,1 \right ),\left (2,5 \right ) ,\left ( 5,2 \right ), \left ( 3,4 \right ),\left ( 4,3 \right )\right \}$$
It has all reverse pairs so it is symmetric,
It has no self pairs, so it is not reflexive.
It is not transitive also because if $\left ( 3,4 \right )$ and $\left ( 4,3 \right )$ belongs to R then $\left ( 3,3 \right )$ must belong to R which is false in given relation...
So option $C$.