Here in question it is given that combination of every two attributes is candidate key.So different combination of 2 attribute possible is $\binom{5}{2}$ i.e 10(AB,AC,AD,AE,BC,BD,BE,CD,CE,DE).
Total subset of {A,B,C,D,E} is 2^5-1(for phi)=31.
All the subset will definitely be super key accept those with single element i.e {A},{B},{C},{D},{E}.
Now the remaining subset will be of length 2 or 3 or 4 and they will definitely contain the combination of two attribute or more than it .
For eg:-{A,B},{B,C}.............{A,B,C},{B,C,D}....... and so on .......
So the only 5 possible singleton subset are not super key .All other are super key .
31-5=26.