Relation Schema means how a relation is defined.
For example, a STUDENT schema will be something like this: $(rollno: integer, name: string, dob: date)$
or we can also remove the practicalities like the domain specification, and simply write:
$STUDENT (rollno, name, dob)$
A schema is usually denoted by uppercase letters.
A relation, on the other hand, is the actual table that we have in the database, it will have some values in it.
For example, a relation student, which can be defined using the STUDENT schema is written like, $student(STUDENT)$.
A relation is usually written in lowercase.
Sometimes, schema name is not mentioned, and is omitted. like $student (rollno, name, dob)$
In your example, the database has two relations(tables) r and s. The schema used for r is R, and for s is S. And the schema R will have an attribute A, along with other attributes. Just like $rollno$ is an attribute for schema $STUDENT$.