The questions says,
This evaluates to there exists a z for which $\sim \left ( P(z) \rightarrow (\sim Q(z) \rightarrow P(z)) \right )$ is True.
But $\sim \left ( P(z) \rightarrow (\sim Q(z) \rightarrow P(z)) \right )$ is always False.
Therefore, saying that $\exists z \sim \left ( P(z) \rightarrow (\sim Q(z) \rightarrow P(z)) \right )$, is False for all cases as there exists no such z. Therefore, this is a contradiction.