The number of ways to seat $n$ people at a round table is $(n-1)!$
Two people can sit together in $2!$ ways
$P1P2 $ or $P2P1$
seat them anywhere, and seat the rest in $(n-2)!$ ways
So, the total number of ways for two people together and rest is $2*(n-2)!$
P(2 sit together ) = $2*(n-2)! / (n-1)!$
P(not 2 sit together) = $1 - 2*(n-2)! / (n-1)! $
= $1 - 2*/ (n-1) $
= $ n-3/n-1$