This problem counts the number of perfect matchings in complete graph on 2n vertices. You can list down the numbers (vertices) as follows and " - " between the numbers indicate edges. The following arrangement represents one of the perfect matchings in complete graph on 2n vertices. If we permute the following matching edges in n! ways the matching doesnt change. Also, the matching remains unchanged if the vertices of a matching edge are permuted. Hence, there are (2n)! / 2^n * n! distinct perfect matchings.
1-2 3-4 ............................................. (2n-1) - (2n)