The probability of coming up heads on an odd toss is either:
(A) You come up heads on the first toss, or
(B) You come up tails on the first two tosses, then come up with heads on an odd toss
These two cases are mutually exclusive, so the total probability is the sum of the two cases
Call your final result P
$P=\frac{1}{2}+\frac{1}{2}.\frac{1}{2}P$
$\frac{3}{4}P=\frac{1}{2} $
$P=\frac{2}{3}$.