In simple words:
Relation Algebra is procedural because there we specify What we want, How we want the output with exact order of operations.
Where as Relational Calculus is a Abstract method for declaring Formal Lang. It just mentions What we want. It never describes how to compute that output.
Eg.
Relational Algebra
$σsubject = "database" and price = "50"(Books)$
Relational Calculus
{${b.bookSubject | Books(b) \Lambda b.bookPrice = 50}$}
Output
Selects tuples from books where 'price' is 50. (RA)
Prints Subject of book having price 50. (RC)