First keep this things in mind that
1.If a language $L$ and its complement $L^{'}$ are recursive enumaerable then $L$ is recursive.
2.The complement of recursive language is recursive.
3.Recursive langauge(rec) are decidable
4. Recursive enumerabale(RE) language are semidecidable.
Let $L=$Recursive Enumerable language be closed under complementation.
Then $L$,$L^{'}$ will be RE and hence $L$ will be Rec (point -1) and thus decidable (point -2)but $L$ is semidecidable (point -4), a contradiction!