Property of the definite integration$:$
$\int_{0}^{2a}f(x)dx=\left \{ 2\int_{0}^{a}f(x)dx ;f(2a-x)=f(x) \right \}$
$\int_{0}^{2a}f(x)dx=\left \{ 0; f(2a-x)=-f(x) \right \}$
Now in your question $I=\int_{0}^{\pi }sin^4(x).cos^5(x)dx$
$I=\int_{0}^{2(\frac{\pi}{2}) }sin^4(x).cos^5(x)dx$
Here $f(x)=sin^4(x).cos^5(x)$
Now,find$f(\pi-x)=sin^4(\pi-x).cos^5(\pi-x)$
$f(\pi-x)=sin^4(x.)(-cos^5(x))$ $[cos(\pi-x) = -cos(x) ,sin(\pi-x) = sin(x)]$
$f(\pi-x)=-sin^4(x.)cos^5(x)=-f(x)$
So,$I=\int_{0}^{\pi }sin^4(x).cos^5(x)dx=0$ [From the above property]