Functionally complete: A collection of logical operators is called functionally complete if every compound proposition is logically equivalent to a compound proposition involving only these logical operator.
Suppose, we prove that (p$\vee$q) $\equiv$ $\sim$($\sim$p $\wedge\sim$q) .
proof: $(p\vee q)$
=$\sim(\sim(p\, \vee q))$ by applying Double Negation Law
=$\sim(\sim p\, \wedge\sim q)$ by applying demorgan law,
Hence, proved.
Now, we can say that $\sim$ , $\wedge$ are functionally complete because resultant compound proposition $\sim(\sim p\, \wedge\sim q)$ contain only these logical operator.