Option A is false. Consider a relation with $3$ attributes where only one is the candidate key. By choosing from any subset of the remaining $2$ attributes including empty set we get $2^2 = 4$ super keys.
Option B is false as any of the candidate key can be chosen as the primary key without any special requirement.
By definition a prime attribute is any attribute part of "some" candidate key. So, option C is false and D is true.
Correct option: D.