Eigen values of real Hermition (a complex square matrix that is equal to its own conjugate transpose) matrix are real.
$\text{For Real Symmetric matrix}: A = A^{T}$
$\text{For Hermition matrix}: A = A^{\theta} = (\;\overline{A}\;)^{T}$
Let $A = \begin{bmatrix}
2 & 3+i & 6 \\
x & 3 & 2 \\
1 & 4 & 3
\end{bmatrix}$
$\implies \overline{A} = \begin{bmatrix}
2 & 3-i & 6 \\
\overline{x} & 3 & 2 \\
1 & 4 & 3
\end{bmatrix}$
$\implies A^{\theta} = (\;\overline{A} \;)^{T} = \begin{bmatrix}
2 & \overline{x} & 1 \\
3-i & 3 & 4 \\
6 & 2 & 3
\end{bmatrix}$
$\text{For Hermition matrix}: A^{\theta} = (\;\overline{A}\;)^{T} = A$
$\implies \begin{bmatrix}
2 & \overline{x} & 1 \\
3-i & 3 & 4 \\
6 & 2 & 3
\end{bmatrix} = \begin{bmatrix}
2 & 3+i & 6 \\
x & 3 & 2 \\
1 & 4 & 3
\end{bmatrix}$
Here, $x = 3 - i.$
So, the correct answer is $(C).$