For $n$ nodes the number of distinct binary trees is $^{2n}C_n*n!/(n+1)$. For $6$ nodes we have $95040$ trees possible. Also with $6$ nodes total $40$ heaps are possible ($20$ each for min and max heaps as shown at end).
Therefore required probability is $40/95040 = 1/2376.$
For a max-heap with $6$ nodes, we have $3$ levels. Total possible min-heaps $=\dfrac{6!}{6\times 3\times 2} = 20.$ (We have only one way to select the root. The two subtrees of the root will have $3$ and $2$ elements. But instead of $3!$ and $2!$ possibilities as in a binary tree, in a max-heap, the number of possibilities will be just $2$ and $1$ respectively as the parent node gets fixed.