Relational algebra has $6$ basic relational operation.
- Select $(\sigma )$
- Project $(\pi )$
- Union $(\cup )$
- Set difference$(-)$
- Cartisian product $(\times )$
- Rename $(\rho )$
Other Operations like Divide $(/)$ can be derived using the basic 6 operators.
So,Only option (D) has derived operator , So Correct answer is option (D).