Average CPI = $1*0.45$ + $3*0.19$ + $5*0.21$ + $0.15*6$ = $2.97$
Clock rate = $250$ $GHz$ , hence Clock cycle time = $1/250$ $GHz$ = $0.004$ $ns$
Average instruction execution time = $0.004 * 2.97$ = $0.01188$ $ns$
This signifies the number of instructions executed in 1ns,
Now by unitary method
in $0.01188$ $*$ $10^{-9}$ second number of instructions executed = $1$
hence in $1s$ number of instructions executed = $\frac{1}{0.01188*10^{-9}}$ = $8.417508*10^{10}$ = $84175.08*10^{6}$
hence MIPS rate = $84175.08$