It is considering
{'A','b','b','d','v','\0'};
as separate code block or you can say separate scope because it is enclosed within two curly braces.
Having said that, consider the below line :
'A','b','b','d','v','\0'
The above line is being treated as a one line statement, much like
int i
As you terminate a statement with a semicolon, it is required in the code provided by you too. So, you make it
'A','b','b','d','v','\0';
You do the same with the next line too and make it as
1,2,3,4;
It is interesting to note that the semicolon after the closing curly brace i.e. after the } is not required so the below code will compile pretty well.
void main(){
{'A','b','b','d','v','\0';}
{1,2,3,4;}
}