For my answer , i am assuming you know what a well ordered set is ,
A nonempty set S ⊆ R is said to be well-ordered if every nonempty subset S has a least element.
For example ---> take a set of non negative integers {0,1,2,3,4,5.....} is a well ordered set and 0 is the least element (this must be unique)
and according to your question, we see
The nonempty subset (0, 1) of S has no least element because as you take 0.001, then i will say 0.000001 is the least, then you will argue, why not 0.00000000001 is the least
We can say that the set of real numbers [0,1] is not a well ordered set as (0,1) is a subset of [0,1] and doesn't have a least element but if this is only taken for integers, then it is well ordered set.
Hence, the interval S = (0, 1) is not well-ordered if taken for real numbers
but if we take (0,1) for integers , it is well ordered .