c) f(x) = x2 + 4 from R to R is not injective
See injective means one to one function
N here is natural number . Range of Natural number is 0 to +infinity
So, natural number has no chances to be many to one or one to many or many to many relationship.
R is real number. Range of Real number -infinity to +infinity.
So, it has a chance of giving same output in positive and negative numbers
Say, for x= -1,1 f(x) = x^2 + 4 from R to R gets same value.
So, C will be answer