Let the age of the husband and wife be 6x and 5x when they got married.
Let present age of husband be H, wife be W, and 1st and 2nd child be a,b.
Average age of the family be 18.5 years. then,
H+W+a+b = 18.5*4 = 74 ---------- 1
Also, The sum of the present ages of the husband and wife is 6.4 times the sum of the present ages of their children. Hence,
H+W = 6.4(a+b) , on substituting in equation no. 1, you get a+b = 10.
also, if a+b = 10 then H+W = 64 ------------------------------------------ 2
the difference between first and second child is of 2 years therefore a = 6 , b = 4 years old.
It means b is younger and a is older, this implies their marriage must have happened before 10 years ago. why?
present age of older child(a or $1^{st}$) = 6 and he was born after 4 years from their marriage, or present age of younger child(b or $2^{nd}$) 4 years and he was born after 6 years from their marriage.
Hence,
H-10+W-10 = 6x + 5x (sum of the age 10 years before from current age = when they got married)
H+W - 20 = 11x
64-20 = 11x (From II)
x = 44/11 = 4
Hence when they married husband's age was 6x = 6*4 = 24 and wife age = 5x = 5*4=20.
They have asked ratio of their ages after second child was born i.e. after 6 years. Hence new ratio will be -
$\frac{H_{new}}{W_{new}} = \frac{24+6}{20+6} = \frac{30}{26} = \frac{15}{13}$ .