Total quantiy of mixture=$30$ liter
ratio of water:milk=$7:3$
So a quantity of water in the mixtrue=$\frac{7}{10}*30=21$ liter
quantity of milk in the mixture=$\frac{3}{10}*30=9$ liter
Let $x$ liter of water be added so the new mixture :
$\frac{21+x}{9}=\frac{6}{1}$
$\implies21+x=54$
$\implies x=33$ liter
Option $(D)$ is correct.