In PCA:
1) The first principal component captures the direction of maximum variance.
2) All principal components are mutually orthogonal (i.e., pairwise perpendicular).
Since principal components are orthogonal eigenvectors of the covariance matrix,
\[
v_i^T v_j = 0 \quad \text{for } i \ne j
\]
Hence, the angle between any two distinct principal components:
\[
\cos \theta = 0
\]
Therefore,
\[
\theta = 90^\circ
\]
Correct option:
\[
{(B)}
\]