DFS gives the reverse postorder:
$3,6,0,5,2,1,4$

This is a valid topological ordering.
However, a DAG can have more than one valid topological ordering whenever some vertices do not have a precedence constraint between them.
In this graph, vertices $1$ and $2$ do not have an edge forcing one to occur before the other.
Therefore, another valid ordering is:
$3,6,0,5,1,2,4$
Check the relevant constraints:
$0$ still appears before $1$ and $2$.
$5$ still appears before $2$.
$1$ still appears before $4$.
All other directed-edge constraints also remain satisfied.
Thus, reverse DFS postorder gives a valid topological ordering, but it need not be the only one.
Answer: A