Let $x$ is the number of $1Rs$ notes and $y$ is the number of $20$ paisa coins.
The amount he,originally, had , $x + (0.20)y$
when he come back after shopping ,then he had, number of $1Rs$ notes is as many as $20$ paisa coins he originally had, and Number of $20$ paisa coins is as many as $1Rs$ notes, he originally had .
so amount now he has, $y + (0.20)x$
Total amount after shopping is reduced by $\frac{2}{3}$.
so $y+(0.20)x = \frac{1}{3} (x+0.20y)$
$3y+0.6x=x+0.2y$
$0.4x = 2.8y$
$x= 7y$ ------(1)
Hariharan originally took the amount for the shopping was greater than $10Rs$ and less than $20 Rs$
$ 10 < x+(0.20)y < 20$ ----(2)
From (1) and (2) ,we get $ x= 14 , y = 2$
So, Total amount, he originally had, $x+0.20y = 14.4$
Amount left after shopping , $y + 0.20x = 4.8$
Amount He spent $= Rs \; 9.6 $