$$\boxed{\text{D. Neither }L_1\text{ nor }\overline{L_1}\text{ is recursively enumerable};\quad L_1\notin RE,\;\overline{L_1}\notin RE}$$
$$
\begin{aligned}
L_1 &: M\text{ halts on every }0^n1^n
\;\rightarrow\; \text{universal condition}
\;\rightarrow\; L_1\notin RE,\\
\overline{L_1} &: M\text{ doesn't halt on at least one }0^n1^n
\;\rightarrow\; \text{non-halting cannot be verified}
\;\rightarrow\; \overline{L_1}\notin RE.
\end{aligned}
$$