$A=\{a^n b^n\mid n\ge1\}$ is a standard DCFL.
The singleton languages $\{a\}$ and $\{b\}$ are finite, so they are regular.
Since DCFL $\cup$ regular is DCFL, both $L_a$ and $L_b$ are DCFLs.
They are still not regular. If $L_a$ were regular, then removing the finite regular language $\{a\}$ would make $A$ regular, which is false.
Same logic works for $L_b$.

So A, B, D, and E are correct.
F is false because DCFLs are not closed under arbitrary union.