$P(Heads) =$$\large \frac{2}{3}$
$P(Tails) =$$\large \frac{1}{3}$
$X_i = 1, when \ heads$
$X_i = 0, when \ tails$
$E(X) = $ $\large 0\left ( \frac{1}{3} \right ) + 1\left ( \frac{2}{3} \right ) = \frac{2}{3}$
$E(X^2) = $$\large 0^2 \left ( \frac{1}{3} \right ) + 1^2\left ( \frac{2}{3} \right ) = \frac{2}{3}$
$Var(X) = E(X^2) - \left [E(X) \right ]^2$
$Var(X) =$$\large \frac{2}{3} - \left [\frac{2}{3} \right ]^2 = \frac{2}{9} $