$A$ is a $n \times n$ matrix i.e. $A$ has $n$ column vectors in $\mathbb{R}^n$.
There exists a vector $x \neq 0$ such that $Ax=0$ this implies the column vectors of $A$ are Linearly Dependent ie $A$ has less than $n$ Linearly Independent column vectors.
Therefore, column vectors of $A$ doesn't span the entire $\mathbb{R}^n$ space. Therefore, there exists some $b$ for which $Az = b$ has no solution.
And for vectors $b$ which are some Linear Combination of column vectors of $A$, since column vectors of $A$ are Linearly Dependent, there are infinite Linear Combinations possible for each vector $b$. Therefore, there exists some $b$ for which $Az = b$ has infinite solutions.
Answer :- E