Given $A=\begin{bmatrix}\cos\alpha & \sin\alpha\\ -\sin\alpha & \cos\alpha\end{bmatrix}$
First, find $A^T$:
$A^T=\begin{bmatrix}\cos\alpha & -\sin\alpha\\ \sin\alpha & \cos\alpha\end{bmatrix}$
Now,
$A+A^T=\begin{bmatrix}\cos\alpha & \sin\alpha\\ -\sin\alpha & \cos\alpha\end{bmatrix}+\begin{bmatrix}\cos\alpha & -\sin\alpha\\ \sin\alpha & \cos\alpha\end{bmatrix}=\begin{bmatrix}2\cos\alpha & 0\\ 0 & 2\cos\alpha\end{bmatrix}$
Since $A+A^T=I$, we compare with $I=\begin{bmatrix}1 & 0\\ 0 & 1\end{bmatrix}$
Therefore, $2\cos\alpha=1$
So, $\cos\alpha=\frac{1}{2}$
For $0\le \alpha<2\pi$, $\alpha=\frac{\pi}{3},\ \frac{5\pi}{3}$
Hence, the correct option is $\boxed{(B)\ \frac{\pi}{3},\ \frac{5\pi}{3}}$