The function is $f(x)=\frac{3x-5}{2x+1}$.
First, $2x+1\neq 0$, so $x\neq -\frac12$. Therefore, the domain cannot be $\mathbb R$. Hence $A=\mathbb R-{-\frac12}$.
Now find the value that $f(x)$ can never take.
Let $y=\dfrac{3x-5}{2x+1}$.
$\Rightarrow y(2x+1)=3x-5$.
$\Rightarrow 2xy+y=3x-5$.
$\Rightarrow 2xy-3x=-y-5$.
$\Rightarrow x(2y-3)=-(y+5)$.
$\therefore x=\frac{-(y+5)}{2y-3}$.
This is defined only when $2y-3\neq 0$, so $y\neq \frac32$.
Thus, the range of $f$ is $\mathbb R-{\frac32}$.
So if $A=\mathbb R-{-\frac12}$ and $B=\mathbb R-{\frac32}$, then every element of $B$ has exactly one preimage in $A$. Therefore, $f$ is both one-one and onto.
Hence $f:\mathbb R-{-\frac12}\to \mathbb R-{\frac32}$ is a bijection.